Simple exploration of 60804-74-2

Here is just a brief introduction to this compound(60804-74-2)Formula: C30H24F12N6P2Ru, more information about the compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)) is in the article, you can click the link below.

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.de Aguirre, Adiran; Funes-Ardoiz, Ignacio; Maseras, Feliu researched the compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)( cas:60804-74-2 ).Formula: C30H24F12N6P2Ru.They published the article 《Four Oxidation States in a Single Photoredox Nickel-Based Catalytic Cycle: A Computational Study》 about this compound( cas:60804-74-2 ) in Angewandte Chemie, International Edition. Keywords: iodoacetanilide alkene oxidative addition reaction nickel catalyst potential barrier; cyclizations; density-functional calculations; nickel; photochemistry; reaction mechanisms. We’ll tell you more about this compound (cas:60804-74-2).

The computational characterization of the full catalytic cycle for the synthesis of indoline from the reaction between iodoacetanilide and a terminal alkene catalyzed by a nickel complex and a photoactive ruthenium species is presented. A variety of oxidation states of nickel, Ni0, NiI, NiII, and NiIII, is shown to participate in the mechanism. Ni0 is necessary for the oxidative addition of the C-I bond, which goes through a NiI intermediate and results in a NiII species. The NiII species inserts into the alkene, but does not undergo the reductive elimination necessary for C-N bond formation. This oxidatively induced reductive elimination can be accomplished only after oxidation to NiIII by the photoactive ruthenium species. All the reaction steps are computationally characterized, and the barriers for the single-electron transfer steps calculated using a modified version of the Marcus Theory.

Here is just a brief introduction to this compound(60804-74-2)Formula: C30H24F12N6P2Ru, more information about the compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)) is in the article, you can click the link below.

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI