In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Photoinduced C(sp3)-N Bond Cleavage Leading to the Stereoselective Syntheses of Alkenes, published in 2019, which mentions a compound: 60804-74-2, mainly applied to alkene Mizoroki Heck synthesis photoinduced bond cleavage Katritzky salt; photoinduced bond cleavage Katritzky salt alkene; C−N bond cleavage; Mizoroki-Heck reaction; alkenes; amines; photoredox catalysis, SDS of cas: 60804-74-2.
Herein we report a versatile Mizoroki-Heck-type photoinduced C(sp3)-N bond cleavage reaction. Under visible-light irradiation (455 nm, blue LEDs) at room temperature, alkyl Katritzky salts react smoothly with alkenes in a 1:1 molar ratio in the presence of 1.0 mol % of com. available photoredox catalyst without the need for any base, affording the corresponding alkyl-substituted alkenes in good yields with broad functional-group compatibility. Notably, the E/Z-selectivity of the alkene products can be controlled by an appropriate choice of photoredox catalyst.
Compound(60804-74-2)SDS of cas: 60804-74-2 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)), if you are interested, you can check out my other related articles.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI