The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 1,2-Benzisoxazole( cas:271-95-4 ) is researched.Synthetic Route of C7H5NO.Soto, R.; Meyer, G.; Viout, P. published the article 《Catalysis and inhibition of two concurrent reactions in cationic micellar medium》 about this compound( cas:271-95-4 ) in Tetrahedron. Keywords: micelle inhibition hydrolysis hydroxybenzaldehyde acyloxime; benzaldehyde acyloxime hydrolysis micelle inhibition; oxime acyl hydrolysis micelle inhibition. Let’s learn more about this compound (cas:271-95-4).
Acid-catalyzed hydrolysis and intramol. nucleophilic anionic cyclization of acyloximes occur concurrently in H2O at pH 7-9; cationic micelles inhibit the hydrolysis reaction. Increasing the length of the acyl chain of 2-HOC6H4CH:NO2CR [R = Me, (CH2)4Me, (CH2)10Me] does not alter the micelle effect, possibly because the environment of the reacting species is not influenced by this variation in the structure.
Compound(271-95-4)Synthetic Route of C7H5NO received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(1,2-Benzisoxazole), if you are interested, you can check out my other related articles.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI