Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 138984-26-6, is researched, Molecular C24H40N4O4Rh2, about Dirhodium(II) caprolactamate: An exceptional catalyst for allylic oxidation, the main research direction is cycloalkene allylic oxidation rhodium; cycloalkenone preparation; rhodium allylic oxidation catalyst.Recommanded Product: 138984-26-6.
The oxidation of organic mols. represents a fundamentally important chem. process. Particularly important is allylic oxidation, whereby a single methylene unit is converted directly into a carbonyl group. Dirhodium(II) caprolactamate, in combination with tert-Bu hydroperoxide, effectively catalyzed the allylic oxidation of a variety of olefins and enones. The reaction was completely selective, tolerant of air/moisture, and can be performed with very low catalyst loading in minutes. A mechanistic proposal involving redox chain catalysis has been put forth, as well as evidence for the intermediacy of a higher valent dirhodium tert-Bu peroxy complex.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI