So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Schwartz, Pierre-Olivier; Moingeon, Firmin; Roeser, Jerome; Couzigne, Emilie; Voirin, Emilie; Masson, Patrick; Mery, Stephane researched the compound: 2-Bromopropanenitrile( cas:19481-82-4 ).Recommanded Product: 19481-82-4.They published the article 《Preparation of multi-allylic dendronized polymers via atom-transfer radical polymerization》 about this compound( cas:19481-82-4 ) in European Polymer Journal. Keywords: multiallylic dendronized polymer atom transfer radical polymerization. We’ll tell you more about this compound (cas:19481-82-4).
Atom-transfer radical polymerization (ATRP) was investigated to polymerize a styrene monomer carrying carbosilane dendrons with 6 terminal allyl branches. Polymers with a monomodal molar mass distribution and low polydispersity have been produced, while by comparison the free-radical polymerization technique led to chain transfer early in the polymerization Steric effect brought by the dendrons result in a slow polymerization rate, leading to an apparent saturation of the d.p. By pushing up the polymerization conditions (eg. increase of temperature or concentration), interchain couplings started to take place, most likely from reactions at the allyl branches. These results are very similar to the ones previously reported for the anionic polymerization of this same multi-allylic dendronized monomer.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI