Aromatic rings are highly stable due to the arrangement of the π-electrons situated above and below the plane of the aromatic ring, which form a π-electron cloud. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article，once mentioned of 32993-05-8, Application In Synthesis of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Treatment of the ruthenium chloride, CpRu(PPh3)2Cl, with the alkynyldithiocarboxylate anions, RCCCS2-, in refluxing THF affords the chelate complexes CpRu(PPh3)(kappa2S,S-S 2CCCR) (1) (R = But (a), Bun (b), Ph (c), SiMe3 (d)) in high yield. The room temperature reaction of the solvated species, [CpRu(PPh3)2(NCPh)]+, with the alkynyldithiocarboxylate anions, RCCCS2-, produces the chelate complexes 1 and the mono-coordinated complexes CpRu(PPh3)2(kappaS- S2CCCR) (2). Complexes 2 are converted to 1 in solution so that they were characterized spectroscopically.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI