Sep-21 News Get Up To Speed Quickly On Emerging Topics: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

If you would like any more information about the 32993-05-8, please don’t hesitate to get in touch, you can email us. HPLC of Formula: C41H35ClP2Ru

Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article,once mentioned of 32993-05-8, HPLC of Formula: C41H35ClP2Ru

The coordination chemistry of bis(di-ortho-tolylphosphino)methane (dotpm) has been studied. It is an excellent chelating ligand and a range of low-valent mononuclear complexes have been prepared; cis-[M(CO)4(eta 2-dotpm)] (M = Cr, Mo, W; 1-3), [CpRuCl(eta2-dotpm)] (4), and cis-[MX2(eta2-dotpm)] (M = Pt, X = Cl, Br, I; 5a-5c, M = Pd, X = Cl; 6). The backbone protons are relatively acidic and can be deprotonated using n-BuLi or LiN(SiMe3)2. Subsequent alkylation by RX (X = halogen; R = Me, Et, CH2Ph) affords cis-[M(CO)4(eta2-Rdotpm)] (M = Cr, Mo, W, R = Me; 7-9, M = Mo, W, R = Et, CH2Ph; 12-15), [CpRuCl(eta2-Medotpm)] (10), and cis-[PtI2(eta2-Medotpm)] (11). Thermolysis of cis-[Mo(CO)4(eta2-Medotpm)] (8) yields what is believed to be the coordinately and electronically unsaturated complex [Mo(CO) 3(eta2-Medotpm)] (16), suggesting that derivatives of dotpm (cone angle 194) are bulky enough to stabilize a 16-electron complex. Crystal structures of 2, 3, 7-9, 13, and 14 have been determined (diphosphine bite angles ranging from 66.58(3) to 70.96(5).

If you would like any more information about the 32993-05-8, please don’t hesitate to get in touch, you can email us. HPLC of Formula: C41H35ClP2Ru

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI