9/27 News What Unique Challenges Do Researchers Face in Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

The π-electrons of these planar compounds are free to cycle around the circular arrangements of atoms found in the aromatic moieties. This stems from the resonance found in planar ring systems, like benzene, and 172222-30-9!, Product Details of 172222-30-9

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Alternating ring-opening olefin metathesis polymerization of trans-RuCl2(Py)2((R,R)-Norphos) and COE using trans-RuCl2(=CHPh)(PCy3)(NHC) (NHC = 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene) as catalyst, followed by cross-linking of the ends of the living polymer with dicyclopentadiene, reaction with (1R,2R)-1,2-diphenylethylenediamine to displace the pyridine ligands, and finally deposition on BaSO4 produced a heterogeneous catalyst that was reused 10 times for hydrogenation of 1?-acetonaphthone in 85% ee.

The π-electrons of these planar compounds are free to cycle around the circular arrangements of atoms found in the aromatic moieties. This stems from the resonance found in planar ring systems, like benzene, and 172222-30-9!, Product Details of 172222-30-9

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI