Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. Related Products of 37366-09-9
Condensation of 1,4-dichloropyridazine with pyrazole, 3,5-dimethylpyrazole and 3-methylpyrazole yielded two types of pyrazolyl-pyridazine ligands, viz., (i) products of substitution on one side of the pyridazine as 3-chloro-6-(pyrazolyl)pyridazine (Cl-L1), 3-chloro-6-(3,5-dimethylpyrazolyl)pyridazine (Cl-L2) and 3-chloro-6-(3-methylpyrazolyl)pyridazine (Cl-L3), and (ii) products of substitution on both sides such as 3,6-bis(pyrazolyl)pyridazine (L1), 3,6-bis(3,5-dimethylpyrazolyl)pyridazine (L2) and tautomers of 3,6-bis(3-methylpyrazolyl)pyridazine (L3). The reactions of eta6-areneruthenium complexes in methanol with the above mentioned pyrazolyl-pyridazine ligands form mononuclear complexes of the type [(eta6-arene)Ru(Cl-L)(Cl)]+ and [(eta6-arene)Ru(L)(Cl)]+; (arene = benzene and p-cymene; Cl-L = Cl-L1, Cl-L2, Cl-L3; L = L1, L2, L3). All these complexes are characterized by IR, NMR, mass spectrometry and UV-vis spectroscopy. The structures of some representative complexes are established by single crystal X-ray diffraction studies.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI