SDS of cas: 37366-09-9, Researchers are common within chemical engineering and are often tasked with creating and developing new chemical techniques, frequently combining other advanced and emerging scientific areas. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article,once mentioned of 37366-09-9
A cyclopentadienyl ruthenium(II) complex has been immobilized on MCM-41 modified with aminopropyl group through an amide bond formation reaction. FT-IR and UV-vis spectra show successful immobilization of cyclopentadienyl ruthenium complex onto the mesoporous silica surface by utilizing the amino group as a connector. The coordination state of the ruthenium complex is analyzed in detail by XAFS measurements, which indicate that the immobilization process does not influence its coordination geometry. Moreover, the retaining of long range ordering of the mesoporous structure of MCM-41 after grafting is evident from the results of XRD and N2 adsorption-desorption measurements. The resulting material promotes efficiently the hydrosilylation of 1-hexyne to produce vinylsilane with high alpha-selectivity under UV-irradiation at room temperature. Furthermore, the catalyst is recyclable for several catalytic runs without significant loss of its catalytic activity.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI