In an article, published in an article, once mentioned the application of 13815-94-6, Name is Ruthenium(III) chloride trihydrate,molecular formula is Cl3H6O3Ru, is a conventional compound. this article was the specific content is as follows.COA of Formula: Cl3H6O3Ru
The synthesis of ruthenium complexes of cyclopentadienylidene phosphorane ligands C5H3R1-PR22R 3 (a: R1 = H, R2 = R3 = Ph; b: R1 = tBu, R2 = Ph, R3 = Me; c: R1 = H, R2 = R3 = nBu; d: R 1 = H, R2 = Ph; R3 = NHDip with Dip = 2,6-diisopropylphenyl) is described. The influence of steric and electronic effects of these ligands on spectroscopic and structural properties is analyzed by means of NMR spectroscopy and x-ray crystallography. Complexes of the form [Ru(eta5-C5H3R1-PR 22R3)(NCMe)3] [PF6] 23a-c are examined concerning their activity in a representative alkene-alkyne coupling reaction. The influence of the sterically demanding phosphonium ionic tag at the Cp-moiety on the yield and regioselectivity of the coupling of methyl 10-undecenoate with 1-octyne is investigated.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI