Related Products of 20759-14-2, An article , which mentions 20759-14-2, molecular formula is Cl3H2ORu. The compound – Ruthenium(III) chloride hydrate played an important role in people’s production and life.
The ruthenium substituted polyoxomolybdate of the Keggin structure, Q4PRuIII(H2O)Mo11O39 (Q=n-Bu4N), has been synthesized and characterized. The IR spectra show that this compound is isostructural with the known manganese and cobalt analogs. The cyclic voltammogram showed similar redox potentials and the UV-vis spectra showed similar energies for the d-d transitions compared to the corresponding tungstate, Q4PRuIII(H2O)W11O39. The catalytic activity of the molybdate versus tungstate in reactions with molecular oxygen was, however, significantly different. IR and 31P NMR evidence indicated that treatment of Q4PRuIII(H2O)Mo11O39 with oxygen showed no structural changes whereas, for Q4PRuIII(H2O)W11O39, a clear change was observed. This finding probably explains the lack of catalytic activity for the latter in the co-oxidation of cumene and 1-octene to cumyl alcohol and 1-octene oxide. For the molybdenum compound, this reaction took place by a kinetic balance of ruthenium metal-catalyzed autooxidation of cumene to cumene hydroperoxide and the molybdenum catalyzed oxygen transfer from cumene hydroperoxide to 1-octene to yield the products. High catalyst loading led to reaction inhibition whereas low loading and excess cumene led to increased autooxidation.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI