Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10049-08-8, Name is Ruthenium(III) chloride, HPLC of Formula: Cl3Ru.
Reactions of [N12] macrocyclic ligand, L 2HClO4, with RuCl 3, PdCl2, K2[PtCl6], [K 2PtCl4] as well as [M(Ph3P)2Cl 2] (M = Pd or Pt), and [Ru(Ph3P)3Cl 2] produces bimetallic complexes whose analytical data are consistent with the molecular formulae as Ru2LCl4(ClO 4)2 (I), Pd2LCl2(ClO4)2 (II), Pt2LCl6(ClO4)2 (III), Pt 2LCl2(ClO4)2 (IV) and Ru 2LCl2(ClO4)2 (V). Reactions of the ligand with the precursors [M(Ph3P)2Cl2] (M = Pd or Pt), and [Ru(Ph3P)3Cl2], has released all the Ph3P ancillary ligand in solution. Magnetic moment, IR and UV-visible spectroscopic data confirms the encapsulation of metal ions in the macrocyclic cavities through chelation from aza groups of the unsymmetrical imine (CN) and amine (CNHC) functions. The macrocyclic moiety has accommodated both the lower as well as higher oxidation states of metal ions, i.e., Ru(II), Ru(III), Pd(II), Pt(II), and Pt(IV), which shows its flexible nature and capability to form stable complexes.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.HPLC of Formula: Cl3Ru. In my other articles, you can also check out more blogs about 10049-08-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI