In an article, published in an article, once mentioned the application of 10049-08-8, Name is Ruthenium(III) chloride,molecular formula is Cl3Ru, is a conventional compound. this article was the specific content is as follows.Safety of Ruthenium(III) chloride
Mixed piperidine-pentamethylenedithiocarbamate (pip-pmdtc) complexes of Ru(III), Rh(III), Pd(II) and Pt(IV) have been synthesized and characterized.The ruthenium(III), rhodium(III) and platinum(IV) complexes are six-coordinate octahedral, while the palladium(II) complex is four-coordinate square planar as revealed by magnetic moment, IR and electronic spectral data.In Ru(III), Rh(III) and Pt(IV) complexes, coordination occurs through both thiocarbamate sulphur atoms, while in the Pd(II) complex the splitting of the nu(C<*>S) band suggests that only one sulphur atom of the dithiocarbamate is coordinated.Coordination also occurs in all the cases through nitrogen atom of the piperidine base.Ligand field parameters for the Rh(III) complex are reported.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI