Application of 37366-09-9, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery.
The syntheses and characterisations of 1,2-Ph2-3-(eta-C5Me 5)-3,1,2-pseudocloso-IrC2B9H9 1, 1,2-Ph2-3-(eta-C6H 6)-3,1,2-pseudocloso-RuC2B9H9 2, 1,2-Ph2-3-(cym)-3,1,2-pseudocloso-RuC2B9H 9 (cym = p-cymene) 3 and 1,2-Ph2-3-(eta-C6Me 6)-3,1,2-pseudocloso-RuC2B9H9 4 are reported from the reactions between Tl2[7,8-Ph2-nido-7,8-C2B9H 9] and either [{IrCl2(C5Me5)}2] or the appropriate [{RuCl2(arene)}2] species. By 11B NMR spectroscopy all these compounds have pseudocloso geometries, in which the C(1) … C(2) connectivity is broken and an approximately square M(3)C(1)B(6)C(2) face is generated. Crystallographic studies on 2 and 3 confirm this suggestion. It is suggested that distortion in these species arises from steric crowding between the Cphenyl substituents, forced to adopt conformations with high theta values by the presence of the eta-bonded substituent at M(3). Individual gauge for localised orbitals calculations, reported for the first time on transition-metal heteroboranes, reasonably reproduce the (previously assigned) 11B NMR chemical shifts of 3-(eta-C5Me5)-3,1,2-closo-RhC2B 9H11, and allow a tentative assignment of those of 1,2-Ph2-3-(eta-C5Me 5)-3,1,2-pseudocloso-RhC2B9H9.
If you are hungry for even more, make sure to check my other article about 37366-09-9. Application of 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI