37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Formula: C12H12Cl4Ru2
Ruthenium complexes of formula [(eta6-arene)Ru(LL*)- (H2O)][SbF6]2 (arene = C6H 6, p-MeC6H4iPr, C6Me6; LL* = bidentate chelate chiral ligand with PN, PP or NN donor atoms) have been tested as catalyst precursors for the asymmetric 1,3-dipolar cycloaddition of nitrones to methacrolein. The reaction occurs quantitatively with perfect endo selectivity and moderate enantioselectivity (up to 74 % ee). The ruthenium aqua complexes can be prepared from the corresponding chlorides, [(eta6-arene)RuCl(LL*)][SbF6]. Dipolarophile intermediates [(eta6-arene)Ru(PNiPr)(methacrolein)][SbF 6]2 (PNiPr = (4S)-2-(2-diphenylphosphanylphenyl)-4- isopropyl-1,3-oxazoline) as well as nitrone-containing complexes [(p-Me-C 6H4iPr)Ru(PNiPr)(nitrone)][SbF6]2 (nitrone = N-benzylidenephenylamine N-oxide, N-benzylidenemethylamine N-oxide, 3,4-dihydroisoquinoline N-oxide) have been also isolated and characterised. The crystal structures of the chlorides (RRu)-[(eta6-C 6Me6)RuCl(PNiPr)][SbF6], (RRu)- [eta6-C6H6)-RuCl(PNInd)][SbF6] {PNInd = (3aR,8aS)-2-[2-(diphenylphosphanyl)phenyl]-3a,8a-dihydroindane[1,2-d] oxazole} and those of the aqua solvates (RRu)-[(eta6- arene)Ru(PNiPr)-(H2O)][SbF6]2 (arene = C 6H6, C6Me6) were determined by X-ray diffraction methods. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI