Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, name: Dichloro(benzene)ruthenium(II) dimer.
The new ligand, 3-(di-2-pyridylaminomethyl)benzamide, L, which carries two different coordination sites, i.e. the primary amide moiety on one side and a di-2-pyridylamine unit as a strong chelating group on the other side is synthesized. Reaction of chloro-bridged dimers viz., [(I· 6-arene)Ru(mu-Cl)Cl]2 and [Cp*M(mu-Cl)Cl] 2 with two equivalents of the ligand L in methanol followed by the addition of NH4BF4 results the formation of mononuclear complexes of the formulation [(I·6-arene)Ru(L)Cl]BF 4 [arene = C6H6 (1), C10H 14 (2), C6Me6 (3)] and [Cp*M(L)Cl]BF 4 [M = Rh (4); Ir (5)]. All these complexes are characterized by micro analyses, IR, and 1H NMR spectroscopic analyses and finally by single crystal XRD study of some representative complexes. Complexes 3 and 5 show mutual intermolecular hydrogen bonding by amide-amide interactions. Copyright
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI