37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Product Details of 37366-09-9
Hetero-bimetallic polyhydride clusters exhibit a regio- and chemoselective activation of a substrate. The rational synthetic method for hetero-bimetallic polyhydride complexes using readily available halide complexes is reported. The reaction of hetero-bimetallic Ru-Ir trichloride complex, Cp?Ru(mu-Cl)3IrCp?(5a), in 2-propanol in the presence of a base afforded Cp?Ru(mu-H)3IrCp?(6a) by sequential salt metathesis and beta-hydrogen elimination. CpsRu(mu-H)3ML [Cps = Cp?, Cp?; ML = IrCp?, RhCp?, Ru(p-cymene), Ru(benzene)] were also selectively synthesized by reacting a mixture of CpsRuCl/n and [LM(mu-Cl)Cl]2 via the formation of CpsRu(mu-Cl)3ML. The IrCp?, RhCp?, and Ru(arene) complexes, Cp?Ru(mu-H)3IrCp?(6b), Cp?Ru(mu-H)3RhCp?(8), and Cp?Ru(mu-H)3Ru(arene) (10), were newly synthesized by this method. The reaction mechanism was discussed based on the hetero-bimetallic chloro-hydride intermediates. Absence of main group hydride reagents was responsible for maintaining the hetero-bimetallic structure during the introduction of the hydride ligand, which lead to selective formation of dinuclear mixed-metal trihydride-bridged complexes.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 37366-09-9. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI