14/9/2021 News Archives for Chemistry Experiments of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Reference of 32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.

The reactions of PTA (1,3,5-triaza 7-phosphaadamantane) and HMTA (1,3,5,7-tetraazaadamantane) with 1,3-propanesultone or 1,4-butanesultone gave the water soluble zwitterionic derivatives PTA+C3H 6SO3- (1), PTA+C4H 8SO3- (2), HMTA+C3H 6SO3- (3) and HMTA+C 4H8SO3- (4). The crystal structure of HMTA+C3H6SO3 is reported. The coordinative ability of 1-4 towards Pt(II) and Ru(II) has been investigated and the antiproliferative activity of ligands and complexes has been tested in two human ovarian cancer cell lines, A2780 and SKOV3.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI