13-Sep-2021 News Awesome Chemistry Experiments For Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

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Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 172222-30-9, C43H72Cl2P2Ru. A document type is Article, introducing its new discovery., Application In Synthesis of Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

Mechanistically intriguing participation of siloxyalkynes occurs in the intramolecular Ru-catalyzed metathesis with terminal alkenes (see scheme; Ms = methanesulfonyl). Combined with efficient protodesilylation, this process resulted in the development of a new method for the synthesis of highly functionalized enones starting from readily accessible acyclic precursors. Heterocyclic and polycyclic compounds were prepared efficiently, which illustrates the generality of this novel method.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI