Related Products of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Aminoboranes, H2BNRR?, represent the monomeric building blocks from which novel polymeric materials can be constructed via metal-mediated processes. The fundamental capabilities of these compounds to interact with metal centers have been probed through the coordination of H 2BNCy2 at 16-electron [CpRu(PR3) 2]+ fragments. In contrast to the side-on binding of isoelectronic alkene donors, an alternative mono(sigma-BH) mode of aminoborane ligation is established for H2BNCy2, with binding energies only ?8 kcal mol-1 greater than those for analogous dinitrogen complexes. Variations in ground-state structure and exchange dynamics as a function of the phosphine ancillary ligand set are consistent with chemically significant back-bonding into an orbital of B-H sigma* character.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI