Reference of 246047-72-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. In a document type is Article, introducing its new discovery.
Ring closing metathesis of 8-allyl-9-butenylpurines or N,9-diallyl-N-methyl-9H-purin-8-amines with the Grubbs second generation catalyst resulted in fused 9,10-dihydro-6H-azepino[1,2-e]purines or 9,10-dihydro-6H-[1,3]diazepino[1,2-e]purines, respectively. The 8-allyl-9-butenylpurines were prepared from 8-bromo-9-butenylpurines after Stille coupling with allyltributyltin. The N,9-diallyl-N-methyl-9H-purin-8-amines were synthesized from 9-allyl-8-bromopurines after treatment with allylamine in H2O under MW irradiation, followed by methylation with MeI in KOH. The new compounds were tested as inhibitors of lipid peroxidation. 6-Methyl-4-(morpholin-4-yl)-7,10-dihydro-6H-[1,3]diazepino[1,2-e]purine presents interesting results and could serve as a lead compound.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI