8-Sep-2021 News Some scientific research about Dichloro(benzene)ruthenium(II) dimer

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery., Quality Control of: Dichloro(benzene)ruthenium(II) dimer

Reaction between trans-Ir(CO)X(PEt3)2 and PF2X (X=Cl) at 193 K gives Ir(CO)X(PEt3)2PF2X, which rearranges at 298 K to form Ir(CO)X2(PEt3)2PF2 (Z).When X=Br or I, product Z is formed at room temperature, but only traces of the intermediate are detected when X=Br, and none at all when X=I.The end-product have been isolated and characterised by NMR and IR spectroscopy and by analysis, and by reactions with O2, S8, Se; with B2H6; with 2 (M=Ru or Os); and with PtCl2(COD).Reaction with H2G (G=O, S, Se) gives Ir(CO)X2(PEt3)2P’FH(G).Crystal structures are reported for Ir(CO)Cl2(PEt3)2P’F2O, for Ir(CO)Cl2(PEt3)2-mu-(P’F2)RuCl2(p-cymene), and for 2PtCl2.In each molecule the angle IrP’Q (Q=O, Ru, Pt) is unusually wide.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI