7-Sep-2021 News Discovery of Tetrapropylammonium perruthenate

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Reference of 114615-82-6. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 114615-82-6, Name is Tetrapropylammonium perruthenate. In a document type is Article, introducing its new discovery.

In the absence of an oxidant, tetrapropylammonium perruthenate (TPAP) is reduced by 2-undecanol to a low-valent ruthenium species that efficiently catalyzes the isomerization of a wide range of allylic alcohols into the corresponding saturated carbonyl derivatives [Eq.(1)]. R1, R2, R3, R4 = alkyl, aryl, H.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI