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The total synthesis and cytotoxic evaluation of C-9 epimers of herbarumin-II and its C-2 epimer are described for the first time. The key transformations of the synthesis include Wittig olefination, MacMillan alpha-hydroxylation, Pinnick oxidation, Yamaguchi esterification, and intramolecular ring closing metathesis.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI