14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), molecular formula is C38H34Cl2O2P2Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 14564-35-3, Application In Synthesis of Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
The “weak-link approach” for the synthesis of metallomacrocycles has been used to synthesize a series of novel Ru(II) macrocycles in high yield. RuCl2(PPh3)3 has been reacted with two different phosphino-alkyl-ether hemilabile ligands, 1,4-(PPh2(CH 2)2O)2C6H4 and 1,4-(PPh2(CH2)2OCH2) 2C6H4. The hemilabile bidentate ligand coordinates to Ru(II) centers through both the P and O atoms to form bimetallic “condensed intermediates”. The weak Ru-O bonds have been selectively cleaved with CO, 1,2-diaminopropane, and pyridine to yield large open macrocycles. This is the first example of the weak-link approach employed to synthesize macrocycles with Ru, and metal centers in general that have more than four coordination sites.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II). In my other articles, you can also check out more blogs about 14564-35-3
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI