32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 32993-05-8, Quality Control of: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
N3P3(O-C6H4- tBu)5Cl reacts with 4-hydroxybenzylcyanide in acetone in the presence of K2CO3, to give the cyanide ligand N3P3(O-C6H4-tBu) 5(O-C6H4-CH2-CN) (1). The monofunctionalized cyclotriphosphazene, N3P3(O-C6H4-tBu) 5(O-C6H4-CH2-CN), reacted with CpFe(dppe)I and with CpRu(PPh3)2Cl in the presence of NH4PF6 and in CH3OH as solvent to give the monocationic complexes [N3P3(O-C6H4-tBu) 5(O-C6H4-CH2CN) Fe(Cp)dppe]PF6 (2) and [N3P3(O-C6H4-tBu) 5(O-C6H4-CH 2-CN)·Ru(Cp)(PPh3)2] PF6 (3), respectively. Electrochemical as well as chemical oxidation of (2) and (3) with NOBF4 yield the stable dicationic species (2)+ and (3)+. Electrochemical as well as spectroscopic data suggest that ligand (1) behaves like a nitrile ligand. The small influence of the cyclophosphazene ring upon coordination is attributed to the long length of the organic spacer groups. An exponential dependence of Delta31Pcoord with the spacer length was found for several organometallic derivatives of cyclophosphazene.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In my other articles, you can also check out more blogs about 32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI