Reference of 10049-08-8, An article , which mentions 10049-08-8, molecular formula is Cl3Ru. The compound – Ruthenium(III) chloride played an important role in people’s production and life.
The kinetics of ruthenium(III) catalyzed oxidation of L-proline by diperiodatocuprate(III) (DPC) in alkaline medium at constant ionic strength (0.10 mol dm-3) has been studied spectrophotometrically using a rapid kinetic accessory. The reaction showed first order kinetics in [DPC] and [RuIII] and apparently less than unit order dependence each in L-proline and alkali concentrations. A mechanism involving the formation of a complex between the L-proline and the hydroxylated species of ruthenium (III) has been proposed. The active species of oxidant and catalyst were [Cu(OH) 2 (H3IO6)2 (H2IO 6)2]4- and [Ru (H2O) 5OH]2+ respectively. The reaction constants involved in the mechanism were evaluated. The activation parameters were computed with respect to the slow step of the mechanism and discussed. Nauka/Interperiodica 2006.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI