A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article，once mentioned of 32993-05-8, category: ruthenium-catalysts
A new family of three-legged piano stool structured organometallic compounds containing the eta5-cyclopentadienylruthenium(II)/iron(II) fragments {M(eta5-C5H5) (DPPE)}+, {Ru(eta5-C5H5)(PPh3)2}+ and {Ru(eta5-C5H5)(TMEDA)}+ with coordinated thiophene based chromophores, namely 5-(2-thiophen-2-yl-vinyl)-thiophene-2-carbonitrile (L1) and 5-[2-(5-Nitro-thiophen-2-yl)-vinyl]-thiophene-2-carbonitrile (L2) has been synthesized and fully characterized by 1H, 13C, 31P NMR, IR and UV-Vis spectroscopies. Also, electrochemical studies were carried out by cyclic voltammetry and all experimental data are interpreted and compared with related compounds under the scope of NLO properties. Compounds [Ru(eta5-C5H5)(DPPE)(NC(C4H2S)C(H)C(H)(C4H3S))][CF3SO3] (1?Ru) [Fe(eta5-C5H5)(DPPE)(NC(C4H2S)C(H)C(H)(C4H3S))] [PF6] (1Fe) and [Ru(eta5-C5H5)(DPPE)(NC(C4H2S)C(H)C(H)(C4H2S)NO2)][CF3SO3] (4?Ru) were also crystallographically characterized.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Quality Control of: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 32993-05-8, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI