Discovery of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Reference of 32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.

CpRuCl(cod)/NH4PF6 (Cp = cyclopentadienyl, cod = 1,5-cyclooctadiene) is an effective catalyst system for the allylic substitution of cyclic allyl carbonates with nucleophiles. This catalyst system enables the first investigation of the stereochemical course of the ruthenium-catalyzed allylic substitution reaction, in which the reaction proceeds with an overall retention of configuration. The stoichiometric reaction of trans-5-(methoxycarbonyl)cyclohex-2-enyl chloride with Cp*RuCl(cod) (Cp* = pentamethylcyclopentadienyl) gave the unexpected complex Cp*Ru(eta6-C6H5CO2Me) + by the rapid dehydrohalogenation/dehydrogenation of the desired Cp*RuCl2(eta3-C6H8CO 2Me) complex.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 32993-05-8, help many people in the next few years., Electric Literature of 32993-05-8

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI