The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), molecular formula is C38H34Cl2O2P2Ru. In a Article，once mentioned of 14564-35-3, Application In Synthesis of Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
The allyl transfer reaction between Re(CO)5(1-) and <(eta3-allyl)PdCl>2 complexes leads to (allyl)rhenium complexes (eta3-H2CCR1CR2R3)Re(CO)4 (1: R1, R2, R3 = H; 2: R2, R3 = H, R1 = Me; 3: R1, R2 = H, R3 = Me; 4: R1 = H, R2, R3 = Me).The 2-methylallyl complex 2 has been characterized by low-temperature X-ray diffraction.Protonation of 1 with HBF4*OEt2 in CH2Cl2 gives the complex (OC)4Re(OEt2)FBF3 (5), which is a precursor for the 14 e(1-) System “(OC)4Re(1+)”.THF and H2O replace the diethyl ether in 5 to give <(OC)4Re(solvent)2>BF4 (6, 7).The reaction of (OC)2(PPh3)2RuCl2 with AgBF4 yields the complex (OC)2(PPh3)2Ru(FBF3)2 (8), which can be considered as a precursor for the 14 e(1-) cation “(OC)2(PPh3)2Ru(2+)” and reacts with H2O to give <(OC)2(PPh3)BF4 (9).Complexes 5-9 are characterized by IR, 1H-, 13C-, 31P- and 19F-NMR spectroscopy. Key Words: Lewis acids, organometallic / 14e(1-) Systems / Allyl complexes / Rhenium complexes / Ruthenium complexes Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), you can also check out more blogs about14564-35-3
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI