Awesome Chemistry Experiments For Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 32993-05-8. In my other articles, you can also check out more blogs about 32993-05-8

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article,once mentioned of 32993-05-8, Product Details of 32993-05-8

The reaction of rare-earth monoalkyl complexes [Cp2Ln(CH 2SiMe3)(thf)] (Cp = cyclopentadienyl; Ln = Y, Lu) with the ruthenium hydride complex [HRu(dmpe)Cp] (dmpe = bis(dimethylphosphino)ethane) gave the corresponding bimetallic hydride complexes [Cp2Ln(mu-H) (mu-eta1:eta5-C5H4)Ru(dmpe)] (Ln = Y (1a), Lu (1b)). One carbon atom of the Ru-bound Cp ligand bridges to the Ln atom in these complexes. The linkage is formed via a C-H bond activation step. The reaction of 1a with diphenylacetylene led to the formation of [Cp 2Y(mu-H){mu-(Ph)CC(Ph)(C5H4)}Ru(dmpe)], which indicates that the Y-C sigma-bond is significantly more reactive than the Y-H-Ru bond. The reaction of bis(alkyl) complexes [Ln(CH 2SiMe3)2(OC6H3( tBu)2-2,6)(thf)2] (Ln = Y, Lu, tBu = tert-butyl) with [HRu(dmpe)Cp] gave the dimeric products [(OC6H 3(tBu)2-2,6)Ln(mu-H)(mu-eta1: eta5-C5H4){kappa3C,P,P?- CH2(Me)P(CH2)2PMe2}Ru]2 (Ln = Y, Lu) by double C-H bond activation. The complexes were characterized by NMR spectroscopy, X-ray crystal structure analysis (XRD), and elemental analysis.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 32993-05-8. In my other articles, you can also check out more blogs about 32993-05-8

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI