Related Products of 37366-09-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer
The azaborate K2[nido-NB10H11] is gained from nido-NB10H13 and K[BHEt3] in a 1:2 ratio. The anion [NB10H11](2-), which is isoelectronic with [C2B9H11](2-), reacts with [{eta6-(C6R6)RuCl2}2] (R=H, Me), [{eta5-(C5Me5)RhCl2}2], or [Ni(PPh3)2Cl2] to give the azametalla-closo-dodecaboranes MNB10H11 with M=(C6Me6)Ru (2), (C6H6)Ru (3), (C5Me5)Rh (4), and (Ph3P)2Ni (5), respectively. The azametallaborane K[Co(NB10H11)2] (6), which contains a sandwich-type coordinated Co atom, is formed from K2[NB10H11] and CoCl2. The structure of 2*CH2Cl2 was determined by X-ray diffraction. The products 2-6 can be derived from the icosahedral anion [B12H12](2-) on replacing a BH(2-) moiety by the isoelectronic nitrene NH and a BHmoiety by the isolobal metal-complex fragment M. The N atom is six-coor dinated in the cluster skeletons 2-6.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI