Discovery of Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)

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Reference of 92361-49-4. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 92361-49-4, Name is Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.

Compounds (eta5-C5Me5)Ru(L / L)Cl (where L / L is 2PPh3, 1,2-bis(diphenylphosphino)ethane or chiral homologs thereof) form adducts with BF3 that have a 1:2 stoichiometry. When the metal is a center of chirality, i.e. for complexes containing C1-symmetric diphosphines, the reaction takes place stereoselectively. (C) 2000 Elsevier Science S.A.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI