Reference of 301224-40-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 301224-40-8, Name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride. In a document type is Article, introducing its new discovery.
An efficient method for the preparation of new alpha-CF3 alpha-amino acid 1,7-enynes that contain electron-donating and electron-withdrawing groups on the triple bond has been developed that proceeds through a Sonogashira-type coupling reaction. The ring-closing enyne methathesis (RCEYM) of the obtained 1,7-enynes with commercially available Grubbs and Hoveyda catalysts provides access to a series of new cyclic alpha-amino acids. The latter compounds that contain the 1,3-diene moiety are attractive building blocks for the construction of trifluoromethylated polycyclic systems. An efficient method to prepare new alpha-CF3 alpha-amino acid 1,7-enynes that contain different substituents on the triple bond has been developed that proceeds by a Sonogashira-type coupling reaction. The ring-closing enyne methathesis (RCEYM) of the obtained 1,7-enynes with commercially available Grubbs and Hoveyda catalysts provides access to a series of new cyclic alpha-amino acids. Copyright
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI