Synthetic Route of 37366-09-9, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery.
A much improved synthesis for the carbagerma-closo-dodecaborate anion [GeCB10H11]- is described in the form of [Bu3NH][GeCB10H11] (1). In reactions with transition metal electrophiles, three transition metal complexes {[Bu 3NH][(C6H6)Ru(Cl)2(GeCB 10H11)] (2), [Bu3NH][Cp*Ir(Cl)(GeCB 10H11)2] (3) and [Me3NH][(PPh 3)2Ir(CO)(GeCB10H11)2] (4)} with metal-germanium bonds were synthesized. The carbagermaborate anion, in the form of the salt [Et3NH][GeCB10H11], and the coordination compounds 2-4 were structurally characterized by single-crystal X-ray diffraction. Computations were carried out for the anions in 1-4 to aid NMR assignments. An improved synthesis of carbagerma-closo-dodecaborate is presented. Coordination compounds with this type of germylene ligands are structurally characterized, and the ligand properties are discussed by using the results of quantum chemical calculations. Copyright
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI