37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Formula: C12H12Cl4Ru2
The 4-, 5- and 6-coordinate complexes <(eta-1-EtOOCC3H4)Pd(tmeda)>BF4, <(eta-1-EtOOCC3H4)Pd(eta-C5H5)>and <(eta-1-EtOOCC3H4)RuCl(eta-C6H6)> have been prepared and characterised, and a crystallographic study of the first undertaken.Crystals are triclinic, Pbar1, with two ion pairs in a cell of dimensions a=7.3077(23), b 8.0643(23), c 15.632(4) Angstroem, alpha 89.255(22), beta 78.834(22) and gamma 76.812(20) deg at 185 K.Using 4429 observed data the structure has been refined to R = 0.0452, and reveals asymmetry in the Pd-allyl bonding such that the substituted carbon atom is nearer to the metal, Pd-C(1) 2.124(4) Angstroem, than is the unsubstituted allyl terminus, Pd-C(3) 2.131(4) Angstroem.To emphasize the significance of this unusual result the structure of the dimeric precursor<(eta-1-EtOOCC3H4)PdCl>2 has been determined.At 291 K one molecule of the dimer crystallises in space group Pbar1 in a cell of dimension a 4.9800(18), b 6.174(3), c 14.080(3) Angstroem, alpha 86.25(3), beta 80.84(3) and gamma 89.44(4) deg (Ci symmetry imposed).The model has been refined to R = 0.0499 for 2239 observed data.In the dimer Pd-C(1) is 2.100(7), Pd-C(3) 2.131(8) Angstroem.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI