Extracurricular laboratory:new discovery of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Related Products of 32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.

Reactions between RuX(PPh3)2(eta-C5H5) (X = Cl, I) and C2(CO2Me)2 in MeOH in the presence of NH4PF6 have given three types of complex, which have been fully characterised by X-ray studies.These are the eta4-diene complexes RuX(eta-C5H5) (1, X = Cl; 2, X = 1) and the eta5-cyclohexadienyl derivatives Ru(eta5-C5H5) (4) and Ru(CO2Me)6> (5).The three complexes are formed by di-, tri- and tetra-merisation of the alkyne at the mononuclear ruthenium centre; the last reaction is unprecedented.Possible mechanisms are discussed.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 32993-05-8, help many people in the next few years., Electric Literature of 32993-05-8

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI