Application of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
The enthalpies of reactions of Cp?RuCl(COD) (Cp?=Cp, Cp* COD=cyclooctadiene) with bis(phosphino)amines of the type Ph2PN(R) PPh2(R=Me 1 or R=Ph 2) and the monochalcogen derivatives Ph2PN(Ph)P(E)Ph2(E=S 3 or Se 4) leading to the formation of Cp?RuCl(PNP) and Cp?RuClPNP(E) complexes, respectively, have been measured by anaerobic solution calorimetry in THF at 30C. These reactions are clean and quantitative. The synthesis and characterization of new organoruthenium complexes is reported. Comparisons with enthalpy data in this two related organoruthenium systems and other similar organometallic systems are also presented.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI