Awesome and Easy Science Experiments about Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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The 1-alkyne-1-thiolates R-C?C-SLi [1a: R = C(CH3)3, 1b: R = C6H11] react with L2PtCl2 (L = PPh3, 1/2 dppe) and CpRu(PPh3)2Cl, respectively to give the complexes trans-(Ph3P)2Pt[S-C?C-C(CH3) 3]2 (2a), cis-dppePt[S-C?C-C(CH3)3]2 (2b), and CpRu(PPh3)2-(S-C?C-R) [3a: R = C(CH3)3, 3b: R = C6H11]. 2a has been characterized by 31P CP/MAS NMR spectroscopy and its crystal structure determined by X-ray diffraction.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI