The Absolute Best Science Experiment for Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Electric Literature of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.

Treatment of with HPPh2 gives the addition product (C5H5)>, 1.The uncoordinated phosphine group of complex 1 reacts with to give the heterobimetallic complex IrCl(CO)2>, 2.Complex 1 reacts with to yield Fe(CO)4>, 3, and with to give the heterometallic complex Mo(CO)5>, 4.Complex 1 also reacts with 2, and to give the homometallic complexes RuCl2(p-cymene)>, 5, Ru3(CO)11>, 6, and Ru3(CO)9(dppee)>, 7, respectively. Keywords: Ruthenium; Iron; Iridium; Molybdenum; Heterometallic complexes; Tridentate phosphines

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI