Reference of 37366-09-9, An article , which mentions 37366-09-9, molecular formula is C12H12Cl4Ru2. The compound – Dichloro(benzene)ruthenium(II) dimer played an important role in people’s production and life.
The synthesis of water-soluble (eta6-arene)ruthenium(II) complexes based on pyrazolyl-naphthyridine ligands modified with a carboxylate group is reported. The complexes are easily accessible in good yields via complexation of [(arene)RuCl2]2 with 7-pyrazolyl-1,8- naphthyridine-2-carboxylic acid (1). All complexes have been characterized by spectroscopic and elemental analyses. The complexes {[Ru(eta6- arene)(N,N?-1)Cl]Cl} (arene = benzene (5), p-cymene (6)) were further confirmed by X-ray diffraction studies. These complexes are soluble in water (ca. 10 mg/mL) and are catalytically active in hydrogen-transfer reduction of carbonyl compounds in aqueous medium with the use of HCOOH/HCOONa as the hydrogen source.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI