Synthetic Route of 32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.
A series of new ruthenium-based derivatives were obtained by reactions of [Ru(eta-C5H5)(PPh3)2Cl]. They are as follows: [Ru(eta- C5H5)(PPh3)2SnF3] (1), [Ru(eta-C5H5)(PPh3)2 SnCl3] (2), [Ru(eta-C5H5)(PPh3)2 SnBr3] (3), [Ru(eta-C5H5)(dppe)SnF3] (4), [Ru(eta-C5H5)(dppe)SnCl3] (5), and [Ru(eta-C5H5)(dppe)SnBr3] (6). Compounds 1-6 were studied by IR, NMR (1H, 13C, 31P and 119Sn) and 119Sn Mo?ssbauer spectroscopies. In addition, 1, 2, 3 and 6 were structurally authenticated by X-ray crystallographic studies. Finally all the derivatives were tested as catalysts in the methanol to acetic acid conversion process, showing promising activities.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI