In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.SDS of cas: 15746-57-3
We have developed a new strategy that uses the Kroehnke synthesis for the preparation of various substituted phenylpyridines in excellent yields (up to 88%). Starting with the appropriate commercially available acetophenone, a variety of phenylpyridines substituted by either electron-donating (i.e. methyl, methoxy) or -withdrawing groups (i.e. bromide, nitro) on the phenyl ring are obtained in a two-step synthesis. The corresponding functionalized cyclometalated ruthenium complexes can be prepared with unusually high yields by using methanol as reaction solvent. The electrochemical data of the complexes demonstrate the strong sigma-donating character of the anionic phenylpyridine ligand. X-ray analyses of four complexes show a shortening of the Ru-C bond associated with the elongation of only one of the five Ru-N bonds (trans effect). Wiley-VCH Verlag GmbH & Co, KGaA, 2006.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI