Reference of 15746-57-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In a document type is Article, introducing its new discovery.
Ruthenafuran and osmafuran monocationic complexes [Ru([14]aneS4)(C?O)]+ or [M(bpy)2(C?O)]+ (C?O = anionic bidentate chelate [C(OR)CHC(Ph)-O]-; [14]aneS4 = 1,4,8,11-tetrathiacyclotetradecane; M = Ru, Os; bpy = 2,2?-bipyridine) have been prepared from reactions between phenyl-ynone HC-C(CO)Ph and [Ru([14]aneS4)Cl2] or [M(bpy)2Cl2] in alcoholic solvents ROH. The formation of metal-vinylidene intermediate, followed by nucleophilic attack by RO-, and carbonyl group coordination to the metal center are believed to be the key steps in the formation of these metallafurans. The nature of the anionic C?O ligand was investigated by electrochemical, spectroscopic, and theoretical means.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI