Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), you can also check out more blogs about32993-05-8
The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article，once mentioned of 32993-05-8, name: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
The Cp(PPh3)2Ru-nCR=CH2 complexes 2 – 4 (n = 0, 2, R = H; n = 3, R = CH3) are prepared by treatment of the chloride 1 with the appropriate organomagnesium halides.The vinyl complex 2 eliminates a PPh3 ligand above 100 deg C and reacts with ethylene (20 – 30 bar) by insertion into the Ru – vinyl bond to give the (eta3-1-methylallyl)ruthenium complex 6a.The 3- and 4-alkenyl compounds 3 and 4 isomerize at 80 – 100 deg C after dissociation of one PPh3 via an (eta2-alkadiene)hydridoruthenium intermediate, e.g. 7, to form the eta3-allyl complexes 6, 8, and 9, respectively.The stable (eta1,eta2-4-alkenyl)ruthenium compounds 10 – 12 are formed if isomerization by beta-H-elimination is prevented by E-configuration of Ru and beta-H in a conformatively inflexible cyclopropyl system.The 31P chemical shifts of 2 – 4 and the (eta1-allyl)ruthenium complexes, of 10 – 12, and of the eta3-allyl complexes 6a, 8, 9, 13a are characteristic for the corresponding type of compounds.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), you can also check out more blogs about32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI