Extended knowledge of Dichloro(benzene)ruthenium(II) dimer

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.HPLC of Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9

37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, HPLC of Formula: C12H12Cl4Ru2

The chloro-bridged metal compounds Cp*(Cl)M(mu-Cl)2M(Cl)Cp* (M = Rh, Ir; Cp* = eta5-C5Me5), (eta6-C6H6)(Cl)Ru(mu-Cl)2Ru(Cl)(eta6-C6H6), and (COD)Ir(mu-Cl)2Ir(COD) react with alpha-amino acidates to give monomeric chelate complexes Cp*(Cl)M(L-L’) (1) (M = Rh, Ir; L-L’ = GlyO, L-ValO, L-PheO, PhenylglyO, L-TrpO, L-ProO, L-HisO, L-AspO, L-azetidine-2-carboxylate), Cp*M(L-AspO,O’) (2) (M = Rh, Ir), +Cl- (3), (eta6-C6H6)(Cl)Ru(L-L’) (4) (L-L’ = L-ProO, L-PheO, L-p-NO2PheO, L-DopaO, D-PhenylglyO), <(eta6-C6H6)Ru(L-HisO)>+Cl- (5), and(COD)Ir(L-L’) (7, 8) (L-L’ = L-AlaO, L-PheO, L-ValO, L-LeuO, L-PhenylglyO, L-1-aminocyclopropanecarboxylate), respectively.The complexes 1-5 have a stereogenic metal atom.Similarly, the cleavage of chloro bridges in (COD)Ir(mu-Cl)2Ir(COD) by alpha-amino acid esters affords the complexes (COD)(Ir(Cl)L (6) (L = GlyOEt, L-AlaOMe, L-ValOMe).The diastereoisomers of 1, 3, and 4 can be detected by NMR spectroscopy.With prolinate a diastereoselectivity up to 92:8 is archieved.The structures of Cp*(Cl)Ir(L-ProO) (1j), Cp*(Cl)Rh(L-azetidine-2-carboxylate) (1m), Cl (3), and (eta-C6H6)(Cl)Ru(L-ProO) (4a) have been determined by X-ray crystallography.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.HPLC of Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI