Application of 32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.
Reactions of metal acetylide complexes M(C{triple bond, long}CAr)(PP)Cp? (M = Fe, Ru; Ar = C6H5, C6H4Me-4; PP = (PPh3)2, dppe; Cp? = Cp, Cp*; not all combinations), or the analogous vinylidene, with cyanogen bromide yield monobromovinylidene complexes [M{C{double bond, long}C(Br)Ar}(PP)Cp?]+, isolated as PF6- salts. The trimethylsilyl-capped acetylides M(C{triple bond, long}CSiMe3)(PP)Cp? react with cyanogen bromide to give [M(C{double bond, long}CBr2)(PP)Cp?]+, the first examples of metal complexes containing a terminal dihalovinylidene ligand, which can be isolated as the BF4- salts. Molecular structures of representative mono- and di-bromovinylidene complexes are reported, together with those of Ru(C{triple bond, long}CSiMe3)(PPh3)2Cp and Ru(C{triple bond, long}CSiMe3)(dppe)Cp*.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI