A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article,once mentioned of 37366-09-9, Formula: C12H12Cl4Ru2
Treatment of [(eta6-C6H6)RuCl2]2 or [(eta6-p-cymene)RuCl2]2 with two equiv. of L-methionine in the presence of AgNO3 and NaOMe gave mononuclear ruthenium(II) complexes [(eta6-C6H6)Ru(L-met)](NO3) (1) and [(eta6-cymene)Ru(L-met)](NO3) (2), respectively. Interactions between equal equiv. of L-methionine and [Ru(CO)2Cl2]n, [Ru(bpy)2Cl2]·2H2O (bpy = 2,2?-bipyridine), [Ru(NO)(PPh3)2Cl3], (Et4N)[Ru(CH3CN)2Cl4] or cis-[Ru(DMSO)4Cl2] (DMSO = dimethylsulfoxide) resulted in isolation of the expected ruthenium complexes [(CO)2Ru(L-met)Cl] (3), [(bpy)2Ru(L-met)]Cl (4), [Ru(L-met)(NO)(PPh3)Cl]Cl (5), [Ru(L-met)(CH3CN)Cl2] (6) and [Ru(L-met)(DMSO)2Cl] (7), respectively. Reaction of [Ru(COD)Cl2]2 (COD = 1,5-cyclooctadiene) with L-methionine gave a dinuclear ruthenium complex [(COD)Ru(mu-S-L-met)(mu-Cl)RuCl(L-metNMe2)] (8). Complexes 1?8 were characterized by microanalyses, IR, NMR and UV?vis spectroscopies. The structures of complexes 1, 2, 4 and 8 have been unambiguously established by single-crystal X-ray crystallography. The photocatalytic properties for hydrogen production by water splitting of complexes 1, 2, 4 and 8 under visible light (lambda > 420 nm) were also investigated.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI