Reference of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
The synthesis of the first example of a bime-tallic complex spanned by the C4H alkynylvinylidene ligand, [Cl(CO)2L 2RuC?CCH=C-RuL2(eta-C5H 5]PF6 (L = PPh3), is reported: the reaction of [Ru(CO)2L3] with butadiyne provides [RuH(C?CC? CH)(CO)2L2], which is converted to the chloro derivative [RuCl(C?CC?CH)-(CO)2L2] by N-chlorosuccinimide. Subsequent treatment with [Ru(thf)L2(eta- C5H5)]PF6 provides [Cl(CO)2L 2RuC? CCH=C=RuL2(eta-C5H 5)]PF6, deprotonation of which affords [Cl(CO) 2L2RuC?CC?CRuL2(eta-C 5H5)].
If you are hungry for even more, make sure to check my other article about 32993-05-8. Synthetic Route of 32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI